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Tuesday, May 5, 2020 | History

6 edition of Activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes found in the catalog.

Activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes

A. E. Shilov

Activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes

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  • 19 Currently reading

Published by Kluwer Academic Publishers in Boston .
Written in English

    Subjects:
  • Alkanes.,
  • Activation (Chemistry),
  • Metal complexes.,
  • Catalysis.

  • Edition Notes

    Includes bibliographical references and index.

    Statementby Alexander E. Shilov, Georgy B. Shul"pin.
    SeriesCatalysis by metal complexes -- v. 21
    ContributionsShulʹpin, G. B.
    The Physical Object
    Paginationxiv, 534 p. :
    Number of Pages534
    ID Numbers
    Open LibraryOL22402551M
    ISBN 100792361016


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General information & study tips.

General information & study tips.

Activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes by A. E. Shilov Download PDF EPUB FB2

Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes. Authors: Shilov, A.E., Shul'pin, Georgiy B. Free Preview. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc.), are especially attractive as substrates for chemical transformations.

This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Paperback – Ma by A.E.

Shilov (Author), Georgiy B. Shul'pin (Author) See all 4 formats and editions Hide other formats and editionsAuthors: Georgiy B. Shul'pin, A.E. Shilov. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes A.E.

Shilov, Georgiy B. Shul'pin, Alexander E. Shilov This monograph is devoted to the activation and various transformations of saturated hydrocarbons (alkanes), i.e.

reactions accompanied by the C--H and C--C bond cleavage. ISBN: OCLC Number: Description: xiv, pages: illustrations ; 23 cm. Contents: Ch. Processes of C-H Bond Activation --Ch. Hydrocarbon Transformations That Do Not Involve Metals or Their Compounds --Ch.

III. Heterogeneous Hydrocarbon Reactions with Participation of Solid Metals and Metal Oxides --Ch. Activation of C-H Bonds by Low-Valent Metal. [PDF] Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Category should be: CHEMISTRY (and not medicine) A.E.

Shilov, Activation and Catalytic Reactions of Saturated Hydrocarbons. Activation and Catalytic Reactions of Alkanes in Solutions of Metal Complexes and 'pin The reactions of saturated hydrocarbons and compounds modelling them with metal complexes, leading to the cleavage of the C-H and C-C bonds, are examined.

In particular, processes which result in the formation of organometallic derivatives areCited by: At last, the list of compounds capable of being activated by metal complexes has been enriched with alkanes.

saturated hydrocarbons, i.e., reactions accompanied by the C–H and C–C bond cleavage. alkane activation in the presence of metal complexes being described in more detail.

Catalysis by Metal Complexes Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes /_8 and ’pin 8. () Activation of Hydrocarbons by Platinum Complexes. In: Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes.

Catalysis by Metal Complexes. Hydrocarbon Activation by Metal Ions, Atoms, and Complexes in the Gas Phase and in a Matrix. Mechanisms of C-H Bond Splitting by Low-Valent Metal Complexes. VII. Activation of Hydrocarbons by Platinum Complexes. VIII. Hydrocarbon Reactions with High-Valent Metal Complexes.

Homogeneous Catalytic Oxidation of Hydrocarbons by Molecular Oxygen. Cite this chapter as: () Hydrocarbon Activation by Metal Ions, Atoms, and Complexes in the Gas Phase and in a Matrix. In: Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes.

Free 2-day shipping. Buy Catalysis by Metal Complexes: Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes (Hardcover) at Get this from a library.

Activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes. [A E Shilov; G B Shulʹpin] -- Annotation This monograph is devoted to the activation and various transformations of saturated hydrocarbons (alkanes), i.e.

reactions accompanied by the C-H and C-C bond cleavage. ACTIVATION OF SATURATED HYDROCARBONS WITH COMPOUNDS OF PLATINUM GROUP METALS (i) Activation of C bonds The starting point in the studies that have for the first time led to the,en- observation of hydrocarbon activation in solutions of metal complexes was ' the above-mentioned analogy with activation of by: H Bond Splitting by Low-Valent Metal Complexes --Activation of Hydrocarbons by Platinum Complexes --Hydrocarbon Reactions with High-Valent Metal Complexes --Homogeneous Catalytic Oxidation of Hydrocarbons Molecular Oxygen --Homogeneous Catalytic Oxidation of Hydrocarbons by Peroxides and Other Oxygen Atom Donors --Oxidation in Living Cells and Its Chemical Models.

Cite this chapter as: () Activation of C-H Bonds by Low-valent Metal Complexes (“The Organometallic Chemistry”). In: Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes. Get this from a library. Activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes.

[A E Shilov; G B Shulʹpin] -- Hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C-H, as well as C-C in various compounds, and.

Cite this chapter as: () Homogeneous Catalytic Oxidation of Hydrocarbons by Molecular Oxygen. In: Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Category should be: CHEMISTRY Springer A.E.

Shilov. Catalysis by Metal ComplexesACS Symposium Series Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes /_4 and.

An introductonary chapter reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed. Separate chapters are devoted to oxidation of saturated, unsaturated and aromatic hydrocarbons, phenols, catechols, oxo-compounds, phosphorus, sulfur and nitrogen compounds.

Author of Activation of Saturated Hydrocarbons by Transition Metal Complexes, Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, and Metal Complexes in Biomimetic Chemical Reactionsn2 Fixation in Solution, Activation and Oxidation of Alkanes, Chemical Models of Photosynthesis5/5(4).

Catalysis by Metal Complexes Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes /_7 and ’pin 7. Proceedings of the Fourth International Symposium on Dioxygen Activation and Homogeneous Catalytic Oxidation.

Edited select article The Selective Functionalisation of Saturated Hydrocarbons. Gif and All That Oxidation of a methyl group in 2, 3-dihydro-2, 2, 4-trimethyl-1H-1, 5-benzodiazepine by o 2 in the presence of metal ions.

Dear Colleagues, Reactions of hydrocarbons and alcohols occurring with the functionalization of C-H bonds can be catalyzed by metal complexes. These transformations are widely applied for organic synthesis, water photo-oxidation, the fixation of CO, CO 2 and N 2, efficient and selective functionalization of C–H bonds in saturated and aromatic hydrocarbons is one of the very important.

Oxidative addition. Oxidative addition is one among a few key elementary reactions of metal complexes. This is a reaction of such compounds as alkali metal halides, RX, acids, HX or dihydrogen, H2, to the metal in a complex which then dissociate into R and X, H and X, or H and H, which are bonded to the metal as two fragment anions.

Fortunately, during the last decades, new catalytic systems based on metal complexes have been discovered, which allow us to introduce various groups into aromatic and even saturated hydrocarbons, as well as other C–H compounds (see, for example, A.

Shilov, G. Shul’pin, “Activation and Catalytic Reactions of Saturated Hydrocarbons. Among hydrocarbons, saturated hydrocarbons (alkanes) are especially attractive as substrates for chemical transformations.

However, these substances are known to be the less reactive organic compounds. In the last decades, new reactions of hydrocarbons. Activation of Hp by metal complexes is known to involve oxidative addition as a primary step in a number of catalytic systems: M + H 2 =^==^ Mmetal atom or ion in a metal complex) If a similar reaction takes place in case of alkanes: M + RH =*==^ M C g it could give rise to consequent reactions, the simplest Cited by:   A related ligand‐assisted four‐centered electrophilic activation is possible (e.g., in lanthanide and actinide hydride or alkyl complexes).

4: The Pt‐cat. nucleophilic attack acc. to the *Shilov reaction (cf. *Pt as cat. metal). 5: A newly developed activation with Rh *sandwich complexes couples linear alkanes with borane reagents to form Author: J. Eppinger. Shilov, A.

& Shul'pin, G. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes (Kluwer Cited by: Such reactions open a new window for achieving C–H activation without the need for transition metal catalysts.

C&#;H activation has usually been achieved by transition metal-mediated by:   Shilov, A. & Shul'pin, G. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes (Kluwer.

Further reading “Activation of C-H Bonds by Metal Complexes”, A. Shilov, G. Shul’pin, Chem. Rev.97, – doi/cr “Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes”, A. Shilov, G. Shul’pin, Kluwer Academic Publishers, Dordrecht/Boston/London, ( p) (Springer, ISBN ).

The Shilov system is a classic example of catalytic C-H bond activation and oxidation which preferentially activates stronger C-H bonds over weaker C-H bonds for an overall partial oxidation.

Overview. The Shilov system was discovered by Alexander E. Shilov in while investigating H/D exchange between isotopologues of CH 4 and H 2 O catalyzed simple transition metal. Book review, Activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes edited by Alexander E.

Shilov and Gregory B. Shul'pin. Appl. Catal., A (), (1), Book review, Spectroscopy of Transition Metal Ions on Surfaces, edited by: Pert M. Weckhuysen, Pascal Van Der Voort, Gabriela Catana. Metal complexes in Si- or Ge-sesquioxane frameworks have been synthesized.

• Some of these complexes catalyzed efficient oxidation of organic compounds. • Alkanes, arenes and alcohols can be oxidized. • Hydrogen peroxide, TBHP and MCPBA have been used as oxidizing reagents. • In many cases the reactions involve hydroxyl by:   Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions.

Chapter 1 offers a comprehensive summary of the main discoveries realized so far. The reaction of the Schiff base (3,5-di-tert-butylhydroxybenzylidene)hydroxybenzohydrazide (H3L) with a copper(II) salt of a base of a strong acid, i.e., nitrate, chloride or sulphate, yielded the mononuclear complexes [Cu(H2L)(NO3)(H2O)] (1), [Cu(H2L)Cl]2MeOH (2) and the binuclear complex [{Cu(H2L)}2(µ-SO4)]2MeOH (3), respectively, with H2L− in the keto form.

Compounds 1–3 were Cited by:. The catalytic activity of a hybrid compound [Fe(salen)-POM] (1) consisting of metallosalen moiety, [Fe III (salen)Cl], covalently linked to a Keggin type polyoxometalate, K 8 SiW 11 O 39 (POM), in the oxidation of hydrocarbons with hydrogen peroxide was on products were identified by gas chromatography and satisfactory yields were by: Georgiy Borisovich Shul’pin (Russian: Георгий Борисович Шульпи́н, also Shulpin) was born in in Moscow, graduated with a M.S.

degree in chemistry from the Chemistry Department of Moscow State University in Between andhe was a postgraduate student at the Nesmeyanov Institute of Organoelement Compounds (Academy of Sciences of the USSR Authority control: BIBSYS:GND:.Alexander E. Shilov (Russian: Шилов, Александр Евгеньевич) (January 1, – June 6, ) was a Russian chemist.

Shilov was born in Ivanovo, Russia, studied Chemistry in Kiev and received his diploma degree in from Kiev State University.

In he began working with Nobel Laureate Nikolay Semyonov toward his Ph.D. at the Academy of Sciences in Moscow.